Here is the full list of all 48 2014 FIFA World Cup Brazil achievements worth 1,000 gamerscore.
Win the FIFA World Cup™ in Road to Rio de Janeiro mode
Advance to City 12 in Road to Rio de Janeiro mode
Complete all scenarios (major objectives) in all 6 FIFA regions in Story of Qualifying
Complete all scenarios (major objectives) in Story of Finals
Complete all group stage objectives in Story of Finals on any difficulty
Complete the Final match (major objective) in Story of Finals on World Class difficulty or higher
Reach 50% of completion or more at least in 3 FIFA regions in Story of Qualifying
Advance to City 6 in Road to Rio de Janeiro mode
Finish (major objectives) at least 1 “EXTRAS” Country in Story of Qualifying
Complete one or more scenario in Story of Qualifying on Legendary difficulty
Qualify as a team from CONCACAF in Road to the FIFA World Cup™ or Captain Your Country modes
Qualify as a team from Africa in Road to the FIFA World Cup™ or Captain Your Country modes
Qualify as a team from Asia in Road to the FIFA World Cup™ or Captain Your Country modes
Win the FIFA World Cup™ as the Captain in Captain Your Country
In the 2014 FIFA World Cup™ Finals get to the R16 without conceding a goal - Semi-Pro or higher
Qualify as a team from Oceania in Road to the FIFA World Cup™ or Captain Your Country modes
Earn Man of the Match in a Captain Your Country game on Semi-Pro or higher
Complete a road without a loss in Road to Rio de Janeiro mode
Purchase your first item in the EASFC catalog
Advance to City 2 in Road to Rio de Janeiro mode
Win your first match in Road to Rio de Janeiro mode
Gift an item to a friend
Match the record set by Brazil in 1958 by scoring 5 or more in the final - Semi-Pro or higher
Score a hattrick in the FIFA World Cup™ final - Semi-Pro or higher
Win a FIFA World Cup™ Finals match by way of a penalty shootout - offline only
Use a quick team set piece during a match
Score 13 goals over the course of the FIFA World Cup™ Finals – Semi-Pro or higher
Score 5+ goals with a single player in a FIFA World Cup™ match - Semi-Pro or higher
Qualify as a team from South America in Road to the FIFA World Cup™ or Captain Your Country modes
Have your player win the Golden Ball in Captain Your Country
Have your player win the Golden Boot in Captain Your Country
Win the FIFA World Cup™ in any offline mode
Match the biggest margin of victory in FIFA World Cup™ history - Win by 9 goals in single player
Qualify as a team from Europe in Road to the FIFA World Cup™ or Captain Your Country modes
Make the final 23 in Captain Your Country
Become Captain in Captain Your Country
Complete 10 adidas miCoach training sessions in CYC, RTWC or FIFA World Cup modes
Get 100% of the point target in an adidas miCoach training drill in CYC, RTWC or FWC mode.
Make the first squad cut in Captain Your Country
Get 10 assists with your player in Captain Your Country
Score a goal on Beginner difficulty
Win the FIFA World Cup™ 5 times to match the all time record set by Brazil
Beat the Community average finish with a 0.5 - 2.5 star team
Win the Online FIFA World Cup™
Win the FIFA World Cup™ with a 3.5 - 4 star team
Win the FIFA World Cup™ with a 2 - 3 star team
Win the FIFA World Cup™ with a 0.5 - 1.5 star team
Beat a friend's best finish in Online FIFA World Cup™