Here is the full list of all 48 FIFA 16 achievements worth 1,000 gamerscore. It takes around 25-30 hours to unlock all of the achievements on Xbox One.
Finish an Online Friendlies Season
Win a Division Title in Online Head to Head Seasons (must be obtained through game-play)
Earn Promotion in Online Head to Head Seasons (must be obtained through game-play)
Have a player score their 50th goal at the club in FIFA Ultimate Team
Copy a Squad from the end of an online match in FIFA Ultimate Team
Use all 7 substitutions in a Pre-Season game in Career Mode
Win a match against the Legendary CPU after being down at half-time
Win a Pre-Season tournament in Career Mode
Sign a world class player in Manager Career mode (80+ rated)
Play 5 training drills in Manager Career Mode
Watch an EA SPORTS News video
Change your captain in FIFA Ultimate Team
Challenge and complete a match against the Team of the Week in FIFA Ultimate Team
Have more than 65% possession in a match
Play a full match with the FIFA Trainer overlays turned on
Assist a goal using a driven ground pass
Win the Women's International Cup tournament
Share an EA SPORTS Football Club Activity
Win a Friendly Season in FIFA Ultimate Team
Score a goal after 10 consecutive passes in the opposing third of the pitch
Score a goal with a curled free kick
Score 2 goals from a corner in a match
During open play, score a long-distance goal with a defender (25 yards out)
Win all 4 matches in a Single Player FUT Draft session in FIFA Ultimate Team
Change your Online Pro haircut
Play a Drop-In Match in Pro Clubs
Win a division title in FIFA Ultimate Team Seasons
Gift an EA SPORTS Football Club Catalogue Item
Sign a Loan Player from the EASFC Catalogue
Have 100% shot accuracy in a match (10 shots minimum on target)
Buy a player from the FUT Transfer Market and earn his loyalty by playing 10 or more games with him
Apply your first Chemistry Style consumable in FIFA Ultimate Team
First match appearance of a player bought from the Transfer Market in FIFA Ultimate Team
Beat an opposing player using no touch dribbling
Complete all basic Skill Games
Get an A grade for all the drills in a Skill Games category
Win a penalty shoot-out
Score 5 goals in a women's football match
Play a women's football match
Perform a slide tackle and keep possession of the ball in a women's football match
Finish a match without conceding a foul against you (off-sides do not count)
Substitute your star player in a match (highest rated player in the team)
Purchase an EA SPORTS Football Club Catalogue Item
Win all 4 matches in an Online FUT Draft session in FIFA Ultimate Team
Improve 1 attribute in Player Career Mode
Complete and win your first Pro Club Seasons league match
Join a club with your Online Pro and play your first match in Pro Clubs
Score a goal with a Flair Shot in a women's football match