Here is the full list of all 48 FIFA 16 achievements worth 1,000 gamerscore. It takes around 25-30 hours to unlock all of the achievements on Xbox One.
Win a Division Title in Online Head to Head Seasons (must be obtained through game-play)
Win a division title in FIFA Ultimate Team Seasons
Win a Friendly Season in FIFA Ultimate Team
Copy a Squad from the end of an online match in FIFA Ultimate Team
Buy a player from the FUT Transfer Market and earn his loyalty by playing 10 or more games with him
Finish an Online Friendlies Season
Earn Promotion in Online Head to Head Seasons (must be obtained through game-play)
Have a player score their 50th goal at the club in FIFA Ultimate Team
Apply your first Chemistry Style consumable in FIFA Ultimate Team
Challenge and complete a match against the Team of the Week in FIFA Ultimate Team
Score a goal with a curled free kick
Win all 4 matches in a Single Player FUT Draft session in FIFA Ultimate Team
Win a match against the Legendary CPU after being down at half-time
Beat an opposing player using no touch dribbling
Use all 7 substitutions in a Pre-Season game in Career Mode
Score 2 goals from a corner in a match
Play 5 training drills in Manager Career Mode
Sign a world class player in Manager Career mode (80+ rated)
Sign a Loan Player from the EASFC Catalogue
Share an EA SPORTS Football Club Activity
First match appearance of a player bought from the Transfer Market in FIFA Ultimate Team
Win a Pre-Season tournament in Career Mode
Improve 1 attribute in Player Career Mode
Complete all basic Skill Games
Get an A grade for all the drills in a Skill Games category
Win the Women's International Cup tournament
Have more than 65% possession in a match
Win a penalty shoot-out
During open play, score a long-distance goal with a defender (25 yards out)
Score a goal after 10 consecutive passes in the opposing third of the pitch
Score a goal with a Flair Shot in a women's football match
Perform a slide tackle and keep possession of the ball in a women's football match
Play a Drop-In Match in Pro Clubs
Complete and win your first Pro Club Seasons league match
Play a full match with the FIFA Trainer overlays turned on
Join a club with your Online Pro and play your first match in Pro Clubs
Assist a goal using a driven ground pass
Have 100% shot accuracy in a match (10 shots minimum on target)
Score 5 goals in a women's football match
Play a women's football match
Substitute your star player in a match (highest rated player in the team)
Change your captain in FIFA Ultimate Team
Finish a match without conceding a foul against you (off-sides do not count)
Change your Online Pro haircut
Gift an EA SPORTS Football Club Catalogue Item
Purchase an EA SPORTS Football Club Catalogue Item
Watch an EA SPORTS News video
Win all 4 matches in an Online FUT Draft session in FIFA Ultimate Team