Full list of all 65 LEGO Marvel's Avengers achievements worth 1,250 gamerscore. It takes around 35-40 hours to unlock all of the achievements in the base game.
The base game contains 40 achievements worth 1,000 Gamerscore, and there are 5 DLC packs containing 25 achievements worth 250 Gamerscore.
Played as Captain Britain, Union Jack, Spitfire, Agent Carter and Mandarin (Trevor Slattery)
Played as Moon Knight, Moondragon and Moon Boy in one session
Played as: Hawkeye (Kate Bishop), Hulkling, Wiccan, America Chavez and Speed in the same session
Grew Ant-Man, Black Goliath, and Fin Fang Foom in one sitting
Died and respawned while playing as Aldrich Killian
Played as Fandral, Hogun and Volstagg in one sitting
Completed 'Korea Prospects'
Completed 'No Strings On Me'
Played as Iron Fist, Daredevil, Jewel (Jessica Jones) and Luke Cage
Completed 'Lost in the Aether'
Visited all Hub locations
Drove Lola as Agent Coulson
Stopped 10 random crimes in Manhattan during a single session
Played as Harley Keener and Tony Stark in any level other than level 9
Played as any version of Falcon and as any version of Cap, while in Washington D.C.
Completed 'Lack of Insight'
Completed 'Ready A.I.M. Fire'
Created and play as a Custom Character equipped with Mjolnir
Died and respawned while playing as Coulson
Played as Vision - both playable characters
Teamed up Nick Fury and Quicksilver
Completed 'Ultron Undone'
Completed 'Rise of Ultron'
Completed 'Anger Management'
Completed 'Earth's Mightiest'
Completed 'Avengers Assemble'
Transformed from Banner to Hulk
Created a Custom Character
Completed 'Helicarrier Havoc'
Completed 'Shakespeare in the Park'
Completed 'Rail Hydra'
Completed 'A Loki Entrance'
Completed 'Struck Off the List'
Achieved True Avenger in any level
Witness the 100% Stud Fountain inside Avengers Tower
Transform from Lou Ferrigno to Hulk (Lou Ferrigno)
Play as every Iron Man variant in one session
Transform into Stan Lee (Hulkbuster)
Unlock and view all 15 Minikit Comic Pages
Turn on all Red Brick Extras at the same time
Complete the 'The Masters of Evil' level
Complete the 'The Masters of Evil' level with all Minikits unlocked
Complete the 'The Masters of Evil' level after achieving True Avenger status
Set both Free Play characters as the Enchantress and Executioner in the Asgard hub area
Defeat 20 enemies as the Black Knight (Dane Whitman) during Free Play
Complete the 'Classic Captain Marvel' level
Complete the 'Classic Captain Marvel' level with all Minikits unlocked
Complete the 'Classic Captain Marvel' level after achieving True Avenger status
Set both Free Play characters as Tic and Hawkeye (Classic)
Fly the Captain Marvel Skycycle as Captain Marvel in the Manhattan hub
Complete the 'Classic Black Panther' level
Complete the 'Classic Black Panther' level with all Minikits unlocked
Complete the 'Classic Black Panther' level after achieving True Avenger status
Complete any race in the HUB using the Black Panther Skycycle
Defeat 20 enemies as Killmonger in the 'Classic Black Panther' level during Free Play
Complete the 'All-New All-Different Doctor Strange' level
Complete the 'All-New All-Different Doctor Strange' level with all Minikits unlocked
Complete the 'All-New All-Different Doctor Strange' level after achieving True Avenger status
Set both Free Play characters as Baron Mordo and Dormammu
Find a way to freeze Doctor Voodoo during Free Play in any area of the game
Complete the 'MARVEL's Agents of S.H.I.E.L.D.' level
Complete the 'MARVEL's Agents of S.H.I.E.L.D.' level with all Minikits unlocked
Complete the 'MARVEL's Agents of S.H.I.E.L.D.' level after achieving True Avenger status
Set both Free Play characters as Agent Leo Fitz and Agent Jemma Simmons
Fly ''The Bus'' vehicle as Agent Melinda May