For this achievement you'll need to accumulate a total of 5,000 Player Points (PP).
This achievement will be a work-in-progress as you casually play the game. Everything you do in the game from Arcade mode, Training, or Ranked/Player Online will earn you Player Points, whether you win or lose. The better you are however, the more PP you'll earn. Once you gain 5,000PP you'll pop this 10G achievement.
P.S. To track your progress you can always view your gaming license at the Main Menu.