For this achievement, you will need to complete the main mission, the 4 Side Ops and the 1 Extra Ops available in the game with the "S Rank".
A FULL WALKTHROUGH of the game can be found
HERE, as well as embedded below. Upon completing the final mission with the S Rank, the achievement will unlock.
Ground Zeroes:
Eliminate the Renegade Threat:
Intel Operative Rescue:
Classified Intel Acquisition:
Destroy the Anti-Air Emplacements:
Jamais Vu: