On the main screen, select LIVE FIXTURES via the EAS FC MATCH DAY menu. Pick your team (any you like), then select from 4 available oppositions.
You can make this achievement as easy or difficult as you like by changing the difficulty level. It is automatically set to Semi Pro but you can change it via the GAME SETTINGS menu, which is available after you've selected your team's and the opposition's kits. You can also change the time to 4 minutes here if you want to get this done quicker.
Now simply win the match and the achievement will pop at the end.