Best way to do is is when you are chipleader an play no limit hold em.
Example:
your chip : 20,000
opponent: 5,000 or less
now safe.
For the achievement you must go all in befor the flop, after the flop, after the turn and after the river and win.
Now just simply go all in and you opponnent will most possibly fold and you win the pot and the chip.