This achievement can be earnt by any player in the game, but is obviously easier with better players on lower difficulties.
The easiest way is to pick a player who you know has a favoured foot. I chose Robin Van Persie.
When collecting the ball, you want to run at an angle diagonal to the goal down the center of the pitch. What I mean by this, is that a player SHOULD use his right foot, but as he is left footed he's going to use the outside of the foot.
Here is a video to show you what you should be aiming for.