Best done on lower difficulties - i just got it in a FUT Cup match.
Just play any match and get behind the defense with a through ball (
).
You'll be one on one with the keeper and what you want to do is quickly dribble in one direction when coming close to him and then going the other direction letting the goalie behind you.
Just score into the empty net and the achievement is yours.
(I even had my shot deflected into the net by a defender who was trying to save it)
cheers for the add from Munhumutapa - tricks surely do work too for this! (using the right stick to do a trick)