I wasn't going to copy and paste my guide from the 360 version unless I knew for sure it works on the Xbox One version. I have just tested it and it indeed still works as of 25/04/2015
(To make this solution dumb proof, you HAVE to be playing as Zer0 the assassin,)
You can unlock this achievement anywhere after level 5 if you follow these simple steps.
1. Go to a catch a ride station.
2. Spawn a Bandit Technical.
You can get this vehicle from Ellie after completing Quests for her. It unlocks after the quest "a dam fine rescue".
3. Go to the back of the Technical and stare at the left side.
4. [First way, How I did it on the Xbox One version]
Stare at the left back side of the technical where you can press (x) to climb in but don't do so yet, activate your deception ability and wait till the timer gets close to zero seconds as possible, when your ability is about to run out climb in the backside left seat of the technical and press A continuously to switch sides you should still be in deception mode and thus gotten the achievement.
(Second way, How I got this on the 360 version)
Activate your special ability AND quickly press X to get onto the back left side of the Technical, now while deception timer is counting down, you need to press A as FAST!! as you can and you will keep sitting left to right on the Technical, for some reason this glitches the timer beyond 10 seconds and thus unlocking this achievement way before level 31.
This method is perfect for those who don't want to restart all over again just to get zero to 31.
May take several tries of trial and error but i can confirm as of 09/10/12 it still works and has not been patched yet for both versions of the Borderlands 2 game.
Both ways above work, tested by me and some friends of mine.
Credit goes to someone apparently on GameFaqs, but it first caught my eye thanks to Drunken Deity's forum post on X360a.
i'm not taking credit for someones find, i am simply sharing it across the community. Thank you and good luck.