This game starts the game of Spider as a 1-suit game by default. First, you need to change these settings. Start a game of Spider and go to the top left side and click the three bars button named menu. Go to Game Options and the first thing available to change is the suits of the game. Choose 2 Suits option.
A new game should appear. Click out of the menu and play!
To win the game you need to pair same suited cards (red with red and black with black). As opposed to freecel, we cannot get a specific game so see my video as an how to play a 2-suited spider game (this is the game that I unlocked the achievement):
If you have any contribution feel free to comment to improve the solution. Happy gaming!