You can get this while going for several of the "gameplay" achievements, but here is the solution if this is the only achievement you are lacking:
First, from the the main menu of FIFA 16, go to the "Customize" tab, select the "Setting & Controls" tile, then the "Game Settings" tile.
From this menu use
to change to the "User Gameplay Customization" menu" - adjust the sliders in your favor (move error settings to 0, move speed settings up to a point which are comfortable with, max out "Goalkeeper Ability", etc.).
Now switch to the "CPU Gameplay Customization" menu & do the opposite to these settings (move speed to 0, error to 100, & especially set "Goalkeeper Ability" to 0, etc.)
Now, navigate back to the main screen, move over to the "Play" tab, "select "Kickoff", select the teams you wish to use (my suggestion is use Barcelona & then some 1/2 star team from England or Ireland). I suggest you change the "Game Settings" before selecting "Play Match", just set the "Difficulty Level" to "Beginner".
At that point, you simply need to score from 25 yards out with a defender. However - as always with FIFA achievements - it's never quite that easy. I scored multiple times with Pique from distances greater than 25 yards, and no achievement. My suggestion is that you shoot from around midway between the kickoff spot (or halfway point or centre spot) and the penalty box. If you shoot from there and score, the achievement almost always pops.