All you need for this is the agents of shield pack.
If you have the pack load up the game and as soon as you can move hold
and select Agent Leo Fitz (if you have all the dlc he is the 2nd from the right 2nd line from the bottom) then swap to the other character and hold
again and select Agent Jemma Simmons (again if you have all the dlc she is on the bottom line 3rd from left) leave in about a minute and achievement should pop :)