For this achievement you need to win a division on ultimate team, please note this means you have to win it you can't just get promoted. The easiest way to get this achievement is by doing the offline competitions, you can find them by going into ultimate team then choosing single player season. I would then recommend choosing the world tour season as it has the easiest matches and the lowest difficulty. Once you choose the competition you want to do you have to win 5/10 matches which should be really easy for you and the achievement is then yours.
If you would like any more help I will leave my video guide below