In any match type grapple your opponent and then hold RB and you will see a person with A, B, X, Y at the bottom of the screen.
Do each of these 4 moves whilst grappling them. (You will need to re-grapple them each time you have done one of the moves)
RB + A
RB + X
RB + Y
RB + B
The achievement will unlock after you have done the 4th one.