This achievement is simply unlocked by doing a reversal that has a orange reversal button
, it oten appear on bigger moves and finishers.
If you are having trouble unlocking this, tilt the odds in your favor. Use a character with a high overall (Lesnar, Cena, Reigns) and face of in an exhibition match vs someone low (Slater, Dalas, Axel). Just let them attack you until you can do the reversal.
To make it more easier, go to settings and put all reversal types on max (sliders all the way to the right) to make reversal moves easier. Also turn off the reverse gauge so you have infinite reversals without waiting for the bar to refill.