When going for this, you can best use a second controller logged in as a guest of friend's profile. Start up a Kick Off match and set the time to 4 min.
Before starting the game, you can also unlock the "
You got skills" achievement (15G) for completing a multiplayer skill game. Just play out the skill game and the achievements is yours.
Then start the match but do NOT score, or kick off and wait untill time's run out with a 0-0 draw. You then get the option to go for a penalty shoot out, choose "penalties". Pick your line up of penalty takers and advance. Once the penalties begin, use the guest/friend's profile to position the keeper on the far left or right end of the goal, making it impossible to get the ball out (if a friend is helping out, let him/her dive to the opposite corner you're gonna shoot). Be sure to score every penalty with your main account. You don't need all 5 penalty's, if your guest/friends account misses one or more penalties, just score yours on the main account to win the game and unlock the achievement.
The way penalties work is a bit different compared to Fifa 17. Aim with
in the opposite corner of the keeper with the arrow green and then hit
untill the arrow is half full, but still green.
Be sure to not waste too much time when taking a penalty. If you wait too long, the penalty will be taken automatically and there's a risk of missing it!