Okay, so there is not a quick way to get this achievement, but I can provide some tips and some schools that helped me learn most of the moves. Make sure to get through the campaign at least once before you start grinding for this. The fastest to get all the moves would be to find a boosting partner and then using your defensive ability to learn the moves faster off each other. You can also double box this achievement if you have two Xbox ones. It's also best to try to browse through leaderboards of schools and see what moves you are missing. You can try out the bare hands of the school at level 1. For you to access the sword moves of a new school you must level up the school to level 3 in combat trials. Make sure you equip all of the content of the school before you go to combat trials.
There's also an NPC (Rakkio) school in Raslan Coliseum who will provide a lot of Stagger moves. He's behind a large metal door in the area and you can only access it once you have defeated Jinn Mesca.
Here's some schools that have some obscure moves that aren't too common. The moves in these schools should stay the same. If the moves change, I don't control that since the schools have been made by other users besides #32898
#69 Credit to Infamous
FEEL FREE TO ADD MORE SCHOOLS IN THE COMMENTS SO WE CAN HELP THE COMMUNITY.
If you don't have the luxury of double boxing or having a boosting partner then here is a link of every move and what NPC may have it. I don't recommend this method because it will take even longer than the method above. https://docs.google.com/spreadsheets/d/13VOW3OilGrba1NPjqVGD...