As micky124 said, any mode will count. But also, each round in Bond Evasion counts as a game played, so a single Bond Evasion game can gain you multiple games toward this achievement.
A way to boost this if you are truly impatient is to start a Bond Evasion and either play it out or just let your controller sit. This, however, will gain you minimal credits and no kills if you don't play.