This achievement unlocks automatically shortly after starting the game and watching the initial cut scene. It is story related and unmissable. It pops as soon as you gain control of the player character.
No game play is required for the achievement--the only requirement is to start the game.
The below video shows the opening, character creation, and the achievement popping. The character is built to get 100% of the achievements on supernova, including DLCs, without having to respec: