This achievement is related to the singleplayer story campaign so this should not be missable.
*** Spoiler - click to reveal ***This achievement is tied to the story mission The Dogs of war where you play as Ms. Marvel. The achievement should pop at the end of the mission when the cut scene starts.
Please message me if you have any questions and if you down vote this please let me know so I can fix this guide and make it better.
Have fun avenging.