Really easy achievement. I personally got it when you get to the mission where you need to break the car window in 104's house. I went around the backside, pick the white fence door lock, and there was a brick right in front of me on the ground. Pressed X when the brick was lined up with window and achievement popped immediately.
You have to have Agility Level 1 unlocked, but you do so just with story progression very early on.