You will probably attain this in normal play. However, if you’re struggling you can follow this method.
From the main menu, go to:
Kick Off -> Local Match.
Choose any 5-star team (for example, Bayern Munich, FC Barcelona, Liverpool R) for your team and any 1-2 star team for your opposition (for example, Waasland-Beveren in the Juliper Pro League).
On the Pre-Match screen, go to the General Settings menu, select a Match Level of Beginner and a Match Time of 5 mins.
Still on the pre-match screen, take your best striker out of the starting line-up and place him on the bench (for example, Lewandowski at Bayern Munich, Messi at Barcelona, Salah at Liverpool).
Start the match. As soon as it has started, pause and go to Game Plan. Substitute the removed player from the bench onto the pitch.
For the rest of the match, aim to get this player to score a goal. You should have around 85 minutes of match time.
The achievement will pop as soon as he scores.