To get this achievement you need to complete the SIRS storyline which is the Spy Games chapter.
This is a spoiler so if you don't care about the story just read on:
This achievement will pop after the cutscene where you are interrogating Richard Malik in your safehouse. He will tell you that your plan will fail and all your operatives and DedSec will fall.
Please leave comments/replies incase I did anything wrong. Feedback is appreciated :)