Here is the full list of all 12 The King of Fighters 2002 Unlimited Match achievements worth 200 gamerscore.
Take the perfect Roaring Sphere using Clark
Defeat 65 opponents in ENDLESS
Defeat 30 opponents in ENDLESS
Defeat 10 opponents in ENDLESS
Defeat Ω Rugal and clear TEAM PLAY
In TEAM PLAY; defeat any of Krizalid, C.Zero, Zero, or Igniz
Defeat Nameless the challenger
Unlock all playable characters
Get a clean hit with Galactica Vanguard using Ralf (available on Practice Mode)
Clear all Normal Challenges
Win a total of 10 RANKED MATCH
Win a total of 30 RANKED MATCH