Another one of the very easy to obtain Achievements in the game, this can simply be earned in a Local game, in the Survival game mode. Choose Sadira as your character and win the first match. If you are struggling, take a few moments to work through the first handful of tutorial dojo sessions in order to familiarize yourself with the combo system. It makes a big difference.
Note that this Achievement will require the purchase of the Sadira character DLC, either individually, with the Combo Breaker Pack, or the Ultra Edition.