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Take optional photo #5 in Episode 2: Out of Time

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4 guidesOffline Game Mode - These achievements require play in game modes that do not necessitate a connection to any online services.Single Player - These achievements can be obtained by a single player.Collectable - These achievements are obtained by exploring the game environment to find a set of unique objects.
SpakonSpakon594,946
24 Mar 2015
15 0 0
Once inside the diner, if you go into the bathroom ( door is to the left of the bar, almost straight ahead of where you come in ) there will be a photo opportunity on the mirror.

Can confirm that if you miss it, coming back to get it through 'Collectibles Mode' will still count towards:

Life is StrangeLab MasterThe Lab Master achievement in Life is Strange worth 66 pointsTake all optional photos in Episode 2: Out of Time